Hierarchical Sb2S3/SnS2/C heterostructure with improved performance for sodium-ion batteries

نویسندگان

چکیده

Metal sulfides are promising anode materials for sodium-ion batteries (SIBs) because of their high theoretical capacities. However, they usually limited by poor cycling performance and rate properties due to large volume expansion sluggish reaction kinetics. Herein, Sb2S3/SnS2/C heterostructures were fabricated directly growing SnS2 nanoplates on Sb2S3 nanorods then coating surface with a carbon layer. Sodium-ion diffusion in several electrodes different electrolytes was further evaluated investigate the electrochemical heterostructures. Results revealed that greatly enhanced material stability promoted ion electron transport. Consequently, composites displayed reversible capacity 642 mA h g−1 at current density 1 A after 600 cycles good 367.3 4 NaPF6-diglyme electrolyte. Therefore, SIBs.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Hierarchical MnCo2O4 nanosheet arrays/carbon cloths as integrated anodes for lithium-ion batteries with improved performance.

To solve the reduced output voltage caused by the high lithium redox potential of Co3O4 when applied as an anode material in full cells, an effective strategy is to partially replace Co by Mn to form MnCo2O4 without changing the original crystal structure. Herein, 3D hierarchical MnCo2O4 nanosheets arrays grown via a hydrothermal method on carbon cloths, as binder-free anodes for lithium-ion ba...

متن کامل

Anode for Sodium-Ion Batteries

DOI: 10.1002/aenm.201500174 The continuous pulverization of alloy anodes during repeated sodiation/desodiation cycles is the major reason for the faster capacity decay. However, if these elements can form a compound (such as Sn 4 P 3 ) after each Na extraction, the pulverization of these elements can be partially repaired and the accumulation of pulverization can be terminated. Therefore, we ca...

متن کامل

Improved electrochemical performance of tin-sulfide anodes for sodium-ion batteries

Due to their highly reversible capacity, tin-sulfide-basedmaterials have gained attention as potential anodes for sodium-ion and lithium-ion batteries. Nevertheless, the performance of tin sulfide anodes is much lower than that of tin oxide anodes. The aim of the present investigation is to improve the electrochemical performances of SnS anodes for sodium-ion batteries using conventional organi...

متن کامل

Sodium and sodium-ion energy storage batteries

1359-0286/$ see front matter 2012 Elsevier Ltd. A http://dx.doi.org/10.1016/j.cossms.2012.04.002 ⇑ Corresponding author. E-mail address: [email protected] (L.F. Nazar). Owing to almost unmatched volumetric energy density, Li-ion batteries have dominated the portable electronics industry and solid state electrochemical literature for the past 20 years. Not only will that continue, but they ar...

متن کامل

High-performance sodium-ion batteries and sodium-ion pseudocapacitors based on MoS(2) /graphene composites.

Sodium-ion energy storage, including sodium-ion batteries (NIBs) and electrochemical capacitive storage (NICs), is considered as a promising alternative to lithium-ion energy storage. It is an intriguing prospect, especially for large-scale applications, owing to its low cost and abundance. MoS2 sodiation/desodiation with Na ions is based on the conversion reaction, which is not only able to de...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Science China. Materials

سال: 2022

ISSN: ['2095-8226', '2199-4501']

DOI: https://doi.org/10.1007/s40843-021-1931-0